潘向强副教授、张正彪教授与朱健教授合作在Chem. Commun. 上发表研究论文

Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl

Jiajia Li ^a, Mengmeng Zhang ^a, Xiangqiang Pan ^*a（潘向强）, Zhengbiao Zhang^*a（张正彪）, Se´bastien Perrier ^bcd, Jian Zhu ^*a （朱健）and Xiulin Zhu^a

^a State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

^b Department of Chemistry, The University of Warwick, Coventry CV4 7AL, UK c Faculty of Pharmacy and Pharmaceutical Sciences, Monash University, 381 Royal Parade, Parkville, Victoria 3052, Australia d Warwick Medical School, The University of Warwick, Coventry CV4 7AL, UK

Chem. Commun., 2019, 55, 7045--7048

A robust method for preparing controlled poly(vinyl ethers) utilizing commercially available reagents under visible light is reported. Pentacarbonylbromomanganese (Mn(CO)₅Br), generated from the conventional photolysis of manganese carbonyl and halide abstraction, is considered as a catalyst to oxidize carbon radical to carbenium ion in this polymerization. Polymerization behavior including the effects of solvents and monomers have been investigated.

链接：https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC03317C#!divAbstract