Fe−S Catalyst Generated In Situ from Fe(III)- and S3 •−-Promoted Aerobic Oxidation of Terminal Alkenes
Jing-Jing Ai1, Bei-Bei Liu1, Jian Li1, Fei Wang1, Cheng-Mi Huang1, Weidong Rao2, and Shun-Yi Wang1,*（汪顺义）
1 Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, China
2Key Laboratory of Biomass-based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
Org. Lett.2021, 23(12) , 4705--4709
An iron–sulfur complex formed by the simple mixture of FeCl3 with S3•– generated in situ from K2S is developed and applied to selective aerobic oxidation of terminal alkenes. The reaction was carried out under an atmosphere of O2 (balloon) and could proceed on a gram scale, expanding the application of S3•– in organic synthesis. This study also encourages us to explore the application of an Fe–S catalyst in organic reactions.
链接：https://pubs.acs.org/doi/10.1021/acs.orglett.1c01408