A non-isolated pentagon rule C82 cage stabilized by a stretched Sc3N cluster
Min Guo‡a, Xiaomeng Li‡a, Yang-Rong Yao b, Jiaxin Zhuang a, Qingyu Meng a, Yingjing Yan a, Xinye Liua and Ning Chen *a（谌宁）
a College of Chemistry, Chemical Engineering and Materials Science, and State Key Laboratory of Radiation Medicine and Protection, Soochow University, Suzhou, Jiangsu 215123, P. R. China
b Department of Chemistry, University of Texas at El Paso, 500 W University Avenue, El Paso, Texas 79968, USA
‡ These authors contributed equally to this work
Chem. Commun., 2021, 57, 4150--4153
A novel cluster fullerene, Sc3N@Cs(39 663)-C82, has been synthesized and characterized. Crystallograpic charaterization unambiguously determines the non-IPR cage structure of Cs(39 663)-C82. Structural analyses further reveal that the Sc3N cluster is notably stretched to facilitate the interaction with the non-IPR fullerene cage.
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