Radical-carbene coupling reaction: Mn-catalyzed synthesis of indoles from aromatic amines and diazo compounds†
Huihuang Li, Yanwei Zhao, Liang Ma, Meihua Ma, Jun Jiang and Xiaobing Wan *（万小兵）
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. China.
Chem. Commun., 2017, 53, 5993--5996
An unprecedented coupling reaction between aromatic amines and diazo compounds was well developed, which afforded a bridge connecting between radical chemistry and metal carbene chemistry. This Mn-catalyzed tandem reaction also provided a fundamentally different and practical approach to the indole skeleton under mild conditions.
链接：http://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC02440A#!divAbstract