The solvent-induced isomerization of silver thiolate clusters with symmetry transformation

Xu-Ran Chen ^a, Ling Yang ^a, Yu-Ling Tan ^a, Hong Yu^*a （虞虹）, Chun-Yan Ni ^a, Zheng Niu^*a （牛政）and Jian-Ping Lang ^*ab（郎建平）

^a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, People’s Republic of China

 ^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, People’s Republic of China

Chem. Commun., 2020, 56, 3649--3652

A novel ligand-stabilized Ag12 nanocluster was synthesized as a model cluster to investigate the solvent-induced isomerization of Ag12 clusters. Another two novel Ag12 clusters as well as their related symmetry transformations were also successfully obtained through the above solvent-induced isomerization process.

链接：https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc01195a#!divAbstract