张松林教授在RSC Adv. 上发表研究论文

Fang Zhang,^a   Ru Wang,^a   San Wu,^a   Peipei Wang^a and   Songlin Zhang*^a （张松林）

 ^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

RSC Adv., 2016,6, 87710-87718

The first utility of neodymium as a mediating-metal in the highly α-regioselective Barbier reaction of diaryl ketones with allyl halides is reported in this paper. This reaction was conveniently carried out under mild conditions in a one-pot fashion with moderate to good yields. The protocol benefited from an availability of starting material, wide substrate scope, and operational simplicity and constituted a powerful alternative approach.

链接：http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra18378f/unauth#!divAbstract