万小兵教授与常州大学Ying Shao教授合作在Org. Lett. 上发表研究论文

Yaxiong Wang^†, Liang Ma^†, Meihua Ma^†, Hao Zheng^‡, Ying Shao^*†‡, and Xiaobing Wan^*† （万小兵）

^† Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

^‡ Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, China

Org. Lett., 2016, 18 (19), pp 5082–5085

A new cross-coupling reaction between sulfonyl hydrazides and diazo compounds has been established, leading to a variety of β-carbonyl sulfones in good yields. This methodology was distinguished by simple manipulation, easily available starting materials, and wide substrate scope. A plausible mechanism involving a radical process was proposed based upon the experimental observations and literature.

链接：http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b02532