汪顺义教授与纪顺俊教授合作在Org. Biomol. Chem. 上发表研究论文

作者: 发布时间:2016-11-24 浏览次数:712

A tetra-n-butylammonium iodide mediated reaction of indoles with Bunte salts: efficient 3-sulfenylation of indoles under metal-free and oxidant-free conditions

Jian Li,a   Zhong-Jian Cai,a   Shun-Yi Wang*a (汪顺义)and  Shun-Jun Ji*a (纪顺俊)

 

aKey Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, P. R. China

 

Org. Biomol. Chem., 2016,14, 9384-9387

 

A highly efficient tetra-n-butylammonium iodide (TBAI) triggered procedure for 3-sulfenylation of indoles with Bunte salts is demonstrated. This protocol provides a simple strategy to prepare 3-alkylthioindoles and 3-arylthioindoles from the corresponding indoles under metal-free and oxidant-free conditions.

 

                                   

 

链接:http://pubs.rsc.org/en/content/articlelanding/2016/ob/c6ob01528j#!divAbstract