徐小平副教授与纪顺俊教授合作在Org. Chem. Front. 上发表研究论文

Xue-Qiang Chu,^a   Zhen-Hua Xing,^a   Hua Meng,^a  Xiao-Ping Xu*^a（徐小平） and   Shun-Jun Ji*^a（纪顺俊）

^aKey Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, People's Republic of China

Org. Chem. Front., 2016,3, 165-169

A Cu-mediated/catalyzed selective oxidative dual C–H bond cleavage of an arene and alkylnitrile or acetone is reported. This method provides a novel approach to highly functionalized fluorene and pyrroloindole derivatives, which are useful in pharmaceutical and photoelectronic areas. In this reaction, two new C(sp³)–C(sp³) and C(Ar)–C(sp³) bonds, a quaternary center and a five-membered ring are simultaneously formed.

链接：http://pubs.rsc.org/en/content/articlelanding/2016/qo/c5qo00329f#!divAbstract