Highly open bowl-like PtAuAgnanocages as robust electrocatalysts towardsethylene glycol oxidation
Hui Xua, Bo Yana, Shumin Lia, JinWanga, PingpingSonga, CaiqinWangb, Jun Guoc, YukouDua,∗(杜玉扣)
a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, PR China
bChemistry Department, University of Toronto, Toronto, M5S3H4, Canada
c Testing & Analysis Center, Soochow University, Jiangsu, 215123, PR China
Journal of Power Sources 384 (2018) 42--47
A novel combined seed mediated and galvanic replacement method has been demonstrated to synthesize a newclass of trimetallicPtAuAgnanocatalysts with highly open bowl-like nanocage structure. The newly-generatedPtAuAgnanocages catalysts exhibit superior electrocatalytic performances towards ethylene glycol oxidationwith the mass activity of 6357.1 mA mg-1, 5.5 times higher than that of commercial Pt/C (1151.1 mA mg-1).This work demonstrates the first example of designing shape-controlled architectures of trimetallic bowl-likePtAuAgnanocages for liquid fuel electrooxidation.

链接:https://www.sciencedirect.com/science/article/pii/S0378775318301885