and （鲍晓光）
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu 215123, China
Org. Lett., 2016, 18 (18), pp 4506–4509
Computational studies were carried out to explore the mechanism of Pd-catalyzed intermolecular C–H amination with O-benzoyl hydroxylamines in which both Pd(0) and Pd(II) catalysts are effective. For the Pd(0)-catalyzed reaction, the generally assumed Pd(0)/Pd(II) catalytic cycle might not be feasible. Instead, Pd(0), being essentially a catalyst precursor, could be oxidized to Pd(II), and the C–H amination proceeds through the Pd(II)/Pd(IV) catalytic cycle.
链接：http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b02093