题目：A New Class of PN3-PincerLigands for Metal-Ligand Cooperative Catalysis
报告人: Kuo-WeiHuang, KAUST Catalysis Center and Division of Physical Sciences and Engineering,King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900,Saudi Arabia
地点: 材化部907-1445
时间: 2015年12月15日下午2:00-3:00
Pincer transition metal complexes have versatilereactivities to catalyze many organic transformations and to activate strongchemical bonds. In particular, complexes with ligand derived from tridentatepyridine-based framework exhibit interesting reactivities. It has beendemonstrated that unique bond activation reactions can be achieved througharomatization–dearomatization of the central pyridine ring. We have designedand prepared a series of transition metal catalysts based on a novel class ofpincer-type PN3 ligands which are capableof interacting with the substrates during the reaction. This “metal-ligandcooperative catalysis “model offers unprecedented reactivities. Dehydrogenativecoupling of alcohols and amines was achieved via protonation-deprotonation inthe aromatization-dearomatization process.
1. Li, H.; Zheng, B.; Huang, K.-W. Coord.Chem. Rev.2015, 293-294, 116-138.
2. Huang, K.-W. et al., US ProvisionalPatent Application No. 61/910,XXX(2013).
3. Huang, K.-W. et al., US Patent No.8,598,351 (2013).
4. Huang, K.-W. et al., US PatentApplication No. 13/886,464 (2012).
5. He, L.-P.; Chen, T.; Gong, D.; Lai, Z.-P.;Huang, K.-W. Organometallics2012, 31, 5208.
6. He, L.-P.; Chen, T.; Xue, D.; Eddaoudi, M.;Huang, K.-W. J. Organomet. Chem.2012, 700, 202.
7. Zeng, G.; Chen, T.; He, L.-P; Pinnau, I.;Lai, Z.-P.; Huang, K.-W.Chem. Eur. J.2012, 18, 1594.
8. Qu, S.; Dang, Y.; Song, C.; Wen, M.; Huang,K.-W.; Wang, Z.-X.J. Am. Chem. Soc.2014, 136, 4974
9. Chen, T.; Li, H.; Qu, S.; Zheng, B.; Lai,Z.-P.; Wang, Z.-X.; Huang, K.-W.Organometallics2014, 33, 4152.
SABIC Chair Associate Professor
KAUST Catalysis Center and Division of PhysicalSciences and Engineering, King Abdullah University of Science andTechnology(KAUST), Thuwal 23955-6900, Saudi Arabia
Tel: +966-12-808-0328 E-mail: hkw@kaust.edu.sa
Education
1993-7 B.S. National TaiwanUniversity
2000-4 Ph.D. Stanford University
Academic Careers
2004-7 Goldhaber Distinguished Fellow, Departmentof Chemistry, Brookhaven National Laboratory, Upton, New York, USA
2007-9 Assistant Professor, Department ofChemistry, National University of Singapore
2009- Associate Professor, King Abdullah Universityof Science and Technology
Awards and Recognition
1993-7 Dr. Yuan T. Lee Fellowship, CTCI
2002-4 Regina Casper Stanford Graduate Fellowship,Stanford University
2004-7 Gertrude and Maurice Goldhaber DistinguishedFellowship, BNL
2008 UK-Singapore Partners in Science CollaborationDevelopment Award
2010 KAUST 1stand2ndSeed Fund Awards
2011 Award of Appreciation from King Abdulaziz and hisCompanions Foundation for Giftedness and Creativity (MAWHIBA) and Ministry ofEducation of Saudi Arabia
2012 Asian Core Program Lectureship (Singapore),Danish Chemical Society Lectureship, andRIKEN Visiting Fellowship
2013 Asian Rising Stars Lectureship, 15th AsianChemical Congress
2013-8 SABIC Chair Professorship
2014 Rising Stars Lectureship, 41stInternationalConference of Coordination Chemistry
2014 Top cited Author (2012-2013), Journal ofOrganometallic Chemistry
2015 New Talent: Asia-Pacific, Dalton Trans.
Representative Publications
1. Li, H.; Zheng, B.; Huang, K.-W. “A new class of PN3-pincerligands for metal-ligand cooperative catalysis” Coord. Chem. Rev.2015, 293-294, 116-138.
2. He, L.-P.; Chen, T.; Gong, D.; Lai, Z.-P.; Huang,K.-W. “Enhanced Reactivities Towards Amines By Introducing an Imine Arm to thePincer Ligand: Direct Coupling of Two Amines to Form an Imine Without Oxidant” Organometallics 2012, 31, 5208-5211.
3. Chen, T.; Li, H.; Qu, S.; Zheng, B.; Lai, Z.-P.;Wang, Z.-X.; Huang, K.-W.“Hydrogenation of Esters Catalyzed by RutheniumPN3-Pincer Complexes Containing an Aminophosphine Arm” Organometallics2014, 33, 4152-4155.
4. Zeng, G.; Chen, T.; He, L.-P; Pinnau, I.; Lai,Z.-P.; Huang, K.-W. Chem. Eur. J.2012, 18, 15940-15943.
5. Weng, Z.; Lee, R.; Jia, W.; Yuan, Y.; Wang, W. Xue,F.; Huang, K.-W. “Cooperative Effect of Silver in Copper-CatalyzedTrifluoromethylation of Aryl Iodides Using Me3SiCF3” Organometallics2011, 30, 3229-3232.
(报告联系人：徐庆锋老师）
