赵应声


  姓名:赵应声
  职称:教授、博士生导师

  部门:化学学院
  联系方式:

   Tel86-18662533899

   Email:yszhao@suda.edu.cn


 课题组网站



学历及学术经历:  

20037月西南大学获得学士学位;20087月武汉大学获理学博士学位(导师雷爱文教授);200810–20109月日本名古屋大学从事博士后研究( Prof. Ryoji Noyori/Saito Sumumu 课题组);201010–20129月美国宾州州立大学从事博士后研究( Prof. Chen gong 课题组, 2012年底加入苏州大学材料与化学化工学部开始独立科研工作,历任副教授(2012)、教授(2018),博士生导师(2018年)。

 

基金与论文

主持国家自然科学基金面上项目三项和青年科学基金、江苏省基础研究计划(杰出青年科学基金和青年科学基金)在国际著名化学期刊如J. Am. Chem. Soc.Angew. Chem. Int. Ed., Nat. Commun., ACS Catal., Chem. Sci., Chem. Commun.Org. Lett.等发表学术论文80多篇,发表SCI检索论文被他引1600余次。

 

获奖情况:

青年拔尖人才(2022年); 江苏省杰出青年基金获得者2018);Thieme Chemistry Journal Award (2018); 苏州大学东吴学者(2016;湖北省科学技术奖一等奖(2012); 曾获湖北省优秀博士论文(2008

 

研究方向及领域区域选择性碳氢键活化反应,碳氢键氟官能团化;小分子(COCO2NOO2等)活化天然产物和生物活性分子半合成地研究。

 

代表性科研成果

1.   Jiang, Y.; Li, B.; Ma, N.; Shu, S.; Chen, Y.; Yang, S.; Shi, D.*; Zhao, Y.*,  Photoredox‐Catalyst‐Enabled para‐Selective Trifluoromethylation of tert‐Butyl Arylcarbamates. Angew. Chem. Int. Ed. 2021, 133 (35), 19178-19182.

2.   Fan, W.; Li, Y.; Wang, D.; Ji, S.*; Zhao, Y.*, Iron-catalyzed highly para-selective difluoromethylation of arenes. J. Am. Chem. Soc. 2020, 142(49), 20524-20530.

3.   Zhou, K.; Zhu, Y.; Fan, W.; Chen, Y.; Xu, X.; Zhang, J.; Zhao, Y.*, Late-stage functionalization of aromatic acids with aliphatic aziridines: direct approach to form β-branched arylethylamine backbones. ACS Catal. 2019, 9(8), 6738-6743.

 

4.Tu, G.; Yuan, C.; Li, Y.; Zhang, J.; Zhao, Y.*, A Ligand-Enabled Palladium-Catalyzed Highly para-Selective Difluoromethylation of Aromatic Ketones. Angew. Chem. Int. Ed. 2018, 57 (47), 15597-15601.

 

 

 

                                   

 

 

5.   Yuan, C.; Zhu, L.; Chen, C.; Chen, X.; Yang, Y.; Lan, Y. *; Zhao, Y.*, Ruthenium(II)-enabled para-selective C–H difluoromethylation of anilides and their derivatives.  Nat. Commun. 2018, 9 (1), 1189.

 

6.Yuan, C.; Zhu, L.; Lan, Y.*; Zhao Y*., Ruthenium(II)Catalyzed C−H Difluoromethylation of Ketoximes: Tuning the Regioselectivity from the meta to the para Position. Angew. Chem. Int. Ed. 2018, 57 (5), 1277-1281.

 

 

7.Zhu, Y.; Chen, X.; Yuan, C.; Li, G.; Zhang, J.; Zhao, Y.*, Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids. Nat. Commun. 2017, 8, 14904.

 

 

8.  Wang, C.; Chen, C.; Zhang, J. Guo, K.; Liu, P.; Guan, M.; Yao, Y.*; Zhao, Y.*, Easily Accessible Auxiliary for Palladium-Catalyzed Intramolecular Amination of C(sp2)H and C(sp3)H Bonds at δ- and ε-Positions. Angew. Chem. Int. Ed. 2014, 53, 9884-9888.

9. 1.Li, G.; Li, D.; Zhang, J.; Shi, D.-Q.*; Zhao, Y.*, Ligand-Enabled Regioselectivity in the Oxidative Cross-coupling of Arenes with Toluenes and Cycloalkanes Using Ruthenium Catalysts: Tuning the Site-Selectivity from the ortho to meta Positions. ACS Catal. 2017, 7 (6), 4138-4143.

 

10.Wang, C.; Zhang, L.; Chen, C.; Han, J.; Yao, Y.*; Zhao, Y.*, Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of [gamma]-C(sp3)-H bonds of aliphatic amine substrates. Chem. Sci. 2015, 6 (8), 4610-4614.

 

11.Wang, Q.; Han, J.; Wang, C.; Zhang, J.; Huang, Z.; Shi, D.*; Zhao, Y.*, Highly site-selective sequential alkenylation of oxalyl amide protected phenylpropylamine derivatives via a seven-membered palladacycle. Chem. Sci. 2014, 5 (12), 4962-4967.