Name:Zhu Xiu-lin
Title:Professor
Department:
Contacts:
Tel: 86-512-65111278 (Lab)
Fax: 86-512-65112796 (O)
Email: xlzhu@suda.edu.cn

Group Website

Professor (Polymer Chemistry & Physics)

B.Sc., M.Sc., Ph.D. Zhejiang University (1978-1987)
Research Interests: Polymer Synthesis (“Living”/Controlled Polymerization); Functionalized Macromolecules with Well-defined Architectures; Microwave and Plasma Irradiation Chemistry.
Representative Publications

  1. Jun Cao, Lifen Zhang*, Xiaowu Jiang, Chun Tian, Xiaoning Zhao, Qi Ke, Xiangqiang Pan, Zhenping Cheng* and Xiulin Zhu*, Facile Iron-Mediated Dispersant-Free Suspension Polymerization of Methyl Methacrylate via Reverse ATRP in Water. Macromol. Rapid Commun. 2013, DOI: 10.1002/marc.201300513.
  2. Zhigui Zheng, Wenxiang Wang, Yuan Zhou, Zhengbiao Zhang* and Xiulin Zhu*, Manganese(III) Acetylacetonate Initiated RAFT Polymerizations: An Alternative and Versatile RAFT Initiator. Polym. Chem. 2013, 10.1039/C3PY00879G.
  1. Jinlong Pan, Jie Miao, Lifen Zhang, Zhangyong Si, Changwen Zhang, Zhenping Cheng* and Xiulin Zhu*, Iron-Mediated (Dual) Concurrent ATRP–RAFT Polymerization of Water-Soluble Poly(ethylene glycol) Monomethyl Ether Methacrylate. Polym. Chem. 2013, DOI: 10.1039/C3PY00671A.
  2. Liangjiu Bai, Lifen Zhang, Jinlong Pan, Jian Zhu, Zhenping Cheng* and Xiulin Zhu*, Developing a Synthetic Approach with Thermoregulated Phase-Transfer Catalysis: Facile Access to Metal-Mediated Living Radical Polymerization of Methyl Methacrylate in Aqueous/Organic Biphasic System. Macromolecules 2013, 46, 2060−2066.
  3. Xing Zhu, Nianchen Zhou,* Jian Zhu, Zhengbiao Zhang,* Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*, A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryates in One Pot. Macromol. Rapid Commun. 2013, 34, 1014-1019.
  4. Jindong Zeng, Jian Zhu*, Xiangqiang Pan, Zhengbiao Zhang, Nianchen Zhou, Zhenping Cheng, Wei Zhang and Xiulin Zhu*, Organoselenium Compounds: Development of a Universal “Living” Free Radical Polymerization Mediator. Polym. Chem. 2013, 4, 3453-3457.
  5. Ting Guo, Lifen Zhang, Xiangqiang Pan, Xiaohong Li, Zhenping Cheng* and Xiulin Zhu*, A Highly Active Homogeneous ICAR ATRP of Methyl Methacrylate Using ppm Levels of Organocopper Catalyst. Polym. Chem. 2013, 4, 3725–3734.
  6. Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao, Zhengbiao Zhang* and Xiulin Zhu*, Hydrogen Bonding Assisted Reversible- Deactivation Radical Copolymerization of 4-Vinylpyridine and Styrene: A Facile Approach for Adjusting Polymerization Behavior, Polymer Composition, etc. Polym. Chem.2013, 4, 3575–3581.
  7. Jinlong Pan, Lifen Zhang, Liangjiu Bai, Zhengbiao Zhang, Hong Chen, Zhenping Cheng* and Xiulin Zhu*, Atom Transfer Radical Polymerization of Methyl Methacrylate with a Thermo-Responsive Ligand: Construction of Thermoregulated Phase-Transfer Catalysis in an Aqueous–Organic Biphasic System. Polym. Chem. 2013, 4, 2876–2883.
  8. Jiangyu Li, Nianchen Zhou,* Zhengbiao Zhang, Ying Xu, Xinrong Chen,* Yingfeng Tu, Zhijun Hu, and Xiulin Zhu*, A Smart Cyclic Azobenzene as Pendant Groups on Polymer Chains: Topological Effect of the Cyclization on Thermal and Photoresponsive Properties of the Azobenzene and the Polymer. Chem. Asian J. 2013, 8, 1095-1100.
  9. Weiwei He, Hongjuan Jiang, Lifen Zhang, Zhenping Cheng* and Xiulin Zhu*, Atom Transfer Radical Polymerization of Hydrophilic Monomers and its Applications. Polym. Chem. 2013, 4, 2919–2938.
  10. Xiaofei Zhang, Wenxiang Wang, Kai Guo, Chrys Wesdemiotis, Zhengbiao Zhang* and Xiulin Zhu*, Zero-Valent Metal Catalyzed Radical-Induced Adjustable Removal/Modification of Thiocarbonylthio End Groups of RAFT Polymer at Ambient Temperature. Polym. Chem., 2013, 4, 637–644.
  11. Liangjiu Bai, Lifen Zhang, Yuan Liu, Xiangqiang Pan, Zhenping Cheng* and Xiulin Zhu*, Triphenylphosphine as Phosphorus Catalyst for Reversible Chain-Transfer Catalyzed Polymerization (RTCP). Polym. Chem. 2013, 4, 3069–3076.
  12. Weiwei He, Liang Cheng, Lifen Zhang, Zhuang Liu*, Zhenping Cheng* and Xiulin Zhu*, Facile Fabrication of Biocompatible and Tunable Multifunctional Nanomaterials via Iron-Mediated Atom Transfer Radical Polymerization with Activators Generated by Electron Transfer. ACS Appl. Mater. Interfaces 2013, 5, 9663–9669.
  13. Jian Qin, Lifen Zhang,* Hongjuan Jiang, Jian Zhu, Zhengbiao Zhang, Wei Zhang, Nianchen Zhou, Zhenping Cheng* and Xiulin Zhu*, Controlled Bimodal Molecular-Weight-Distribution Polymers: Facile Synthesis by RAFT Polymerization. Chem. Eur. J. 2012, 18, 6015 – 6021.
  14. Xiangqiang Pan, Jian Zhu, Jianping Zou, Zhengbiao Zhang, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Jian Zhu, Zhijun Hu, Xiulin Zhu*, Straightforward and Highly Efficient Synthesis of Diselenocarbamates. Org. Lett. 2012, 14, 6170-6173.
  1. Gaohua Zhu, Lifen Zhang,* Xiangqiang Pan, Wei Zhang, Zhenping Cheng* and Xiulin Zhu*, Facile Soap-Free Miniemulsion Polymerization of Methyl Methacrylate via Reverse Atom Transfer Radical Polymerization. Macromol. Rapid Commun. 2012, 33, 2121−2126.
  2. Junfei Zhao, Wenxiang Wang, Liangjiu Bai, Lili Zhou, Zhenping Cheng, Zhengbiao Zhang* and Xiulin Zhu*, Reversible-Deactivation Radical Polymerization Mediated by CuSO4·5H2O: An Alternative and Promising Copper(II)-Based Catalyst. Polym. Chem. 2012, 3, 3220–3223.
  3. Wenxiang Wang, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou and Xiulin Zhu*, Favorable Hydrogen Bonding in Room-Temperature Cu(0)-Mediated Controlled Radical Polymerization of 4-Vinylpyridine. Polym. Chem. 2012, 3, 2731–2734.
  4. Weiwei He, Lifen Zhang, Jie Miao, Zhenping Cheng* and Xiulin Zhu*, Facile Iron-Mediated AGET ATRP for Water-Soluble Poly(ethylene glycol) Monomethyl Ether Methacrylate in Water. Macromol. Rapid Commun. 2012, 33, 1067−1073.
  5. Liangjiu Bai, Lifen Zhang, Zhenping Cheng* and Xiulin Zhu*, Activators Generated by Electron Transfer for Atom Transfer Radical Polymerization: Recent Advances in Catalyst and Polymer Chemistry. Polym. Chem. 2012, 3, 2685-2697.
  6. Hao Zhang, Nianchen Zhou*, Xing Zhu, Xinrong Chen, Zhengbiao Zhang, Wei Zhang, Jian Zhu, Zhijun Hu and Xiulin Zhu*, Cyclic Side-Chain Phenylazo Naphthalene Polymers: Enhanced Fluorescence Emission and Surface Relief Grating Formation. Macromol. Rapid Commun. 2012, 33, 184-1851.
  7. Yanna Zhang, Xing Zhu, Nianchen Zhou,* Xinrong Chen, Wei Zhang, Yonggang Yang and Xiulin Zhu*, Cyclic Main-Chain Phenylazo Naphthalene Polymers: Topological Effect on Fluorescence Emission and Photoinduced Surface Relief Grating Formation. Chem. Asian J. 2012, 7, 2217-2221.
  8. Xing Zhu, Nianchen Zhou, Zhengbiao Zhang, Baoquan Sun, Yonggang Yang, Jian Zhu, and Xiulin Zhu*, Cyclic Polymers with Pendent Carbazole Units: Enhanced Fluorescence and Redox Behavior. Angew. Chem. Int. Ed. 2011, 123, 6745-6748.
  9. Gaohua Zhu, Lifen Zhang, Zhengbiao Zhang, Jian Zhu, Yingfeng Tu, Zhenping Cheng* and Xiulin Zhu*, Iron–Mediated ICAR ATRP of Methyl Methacrylate. Macromolecules 2011, 44, 3233–3239.
  10. Ting Guo, Lifen Zhang, Hongjuan Jiang, Zhengbiao Zhang, Jian Zhu, Zhenping Cheng*, Xiulin Zhu*, Catalytic Amounts of Sodium Hydroxide as Additives for Iron–Mediated AGET ATRP of MMA. Polym. Chem. 2011, 2, 2385–2390.
  11. Qiang Li, Lifen Zhang, Liangjiu Bai, Zhengbiao Zhang, Jian Zhu, Nianchen Zhou, Zhenping Cheng* and Xiulin Zhu*, Multistimuli–Responsive Hybrid Nanoparticles with Magnetic Core and Thermoresponsive Fluorescence–labeled Shell via Surface–initiated RAFT Polymerization. Soft Matter 2011, 7, 6958–6966.
  12. Jiliang Liu, Weiwei He, Lifen Zhang, Zhengbiao Zhang, Jian Zhu, Lin Yuan, Hong Chen, Zhenping Cheng* and Xiulin Zhu*, Bifunctional Nanoparticles with Fluorescence and Magnetism via Surface–Initiated AGET ATRP Mediated by an Iron Catalyst. Langmuir 2011, 27, 12684–12692.
  13. Weihua Guo, Jian Zhu, Zhenping Cheng, Zhengbiao Zhang, and Xiulin Zhu*, Anticoagulant Surface of 316 L Stainless Steel Modified by Surface-Initiated Atom Transfer Radical Polymerization. ACS Appl. Mater. Interfaces 2011, 3, 1675–1680.
  14. Zhengbiao Zhang, Wenxiang Wang, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Yonggang Yang, Yingfeng Tu, and Xiulin Zhu*, Zero–valent Iron/RAFT Agent–Mediated Polymerization of Methyl Methacrylate at Ambient Temperature. Macromolecules 2010, 43, 7979–7984.
  15. Liangjiu Bai, Lifen Zhang, Zhengbiao Zhang, Yingfeng Tu, Nianchen Zhou, Zhenping Cheng* and Xiulin Zhu*, Iron–Mediated AGET ATRP of Styrene in the Presence of Catalytic Amounts of Base. Macromolecules 2010, 43, 9283–9290.
  16. Xiaoqiang Xue, Jian Zhu, Zhengbiao Zhang, Nianchen Zhou, Yingfeng Tu, and Xiulin Zhu*, Soluble Main-Chain Azobenzene Polymers via Thermal 1,3-Dipolar Cycloaddition: Preparation and Photoresponsive Behavior. Macromolecules 2010, 43, 2704–2712.
  17. Xu Xu, Nianchen Zhou, Jian Zhu, Yingfeng Tu, Zhengbiao Zhang, Zhenping Cheng and Xiulin Zhu*, The First Example of Main-Chain CyclicAzobenzene Polymers. Macromol. Rapid Commun. 2010, 31, 1791-1797.
  18. Jiliang Liu, Lifen Zhang, Suping Shi, Shuai Chen, Nianchen Zhou, Zhengbiao Zhang, Zhenping Cheng* and Xiulin Zhu*, A Novel and Universal Route to SiO2–Supported Organic/Inorganic Hybrid Noble Metal Nanomaterials via Surface RAFT Polymerization. Langmuir 2010, 26, 14806–14813.
  19. Lifen Zhang, Jie Miao, Zhenping Cheng and Xiulin Zhu*, Iron-Mediated ICAR ATRP of Styrene and Methyl Methacrylate in the Absence of Thermal Radical Initiator. Macromol. Rapid Commun. 2010, 31, 275–280.
  20. Nianchen Zhou, Zhengbiao Zhang, Jian Zhu, Zhenping Cheng and Xiulin Zhu*, RAFT Polymerization of Styrene Mediated by Ferrocenyl-Containing RAFT Agent and Properties of the Polymer Derived from Ferrocene. Macromolecules 2009, 42, 3898-3905.
  21. Zhengbiao Zhang, Wenxiang Wang, Hongda Xia, Jian Zhu, Wei Zhang and Xiulin Zhu*, Single–Electron Transfer Living Radical Polymerization (SET–LRP) of Methyl Methacrylate (MMA) with a Typical RAFT Agent as an Initiator. Macromolecules 2009, 42, 7360–7366.
  22. Lifen Zhang, Zhenping Cheng, Yueting Lü and Xiulin Zhu*, A Highly Active Iron-Based Catalyst System for AGET ATRP of Styrene. Macromol. Rapid Commun. 2009, 30, 543–547.
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