Name:ZHANG Zhengbiao
Tel: 86-512-65880819 (O)


Group Website
Research Interests:
Precise Synthesis of Well-defined Macromolecule, Mechanism of “Living”/Controlled Polymerization; Design and Synthesis of Functional Polymers
Representative Publications:

1.Yuxuan Ji, Liuqiao Zhang, Xue Gu, Wei Zhang, Nianchen Zhou, Zhengbiao Zhang,* and Xiulin Zhu. Sequence-Controlled Polymers with Furan-Protected Maleimide as a Latent Monomer. Angew. Chem. Int. Ed201756, 2328-2333.

2.Wei Chen, Yanyan Zhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu. Shape-memory and self-healing polyurethanes based on cyclic poly(ε-caprolactone). Polym. Chem., 2016, 7, 6789-6797.

3.Junfei Zhao, Yanyan Zhou, Yu Zhou, Nianchen Zhou, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu. A straightforward approach for the one-pot synthesis of cyclic polymers from RAFT polymers via thiol–Michael addition. Polym. Chem., 2016, 7, 1782-1791.

4.Chunlai Ding, Caiwei Fan, Ganquan Jiang, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu* and Xiulin Zhu. Photocatalyst-Free and Blue Light-Induced RAFT Polymerization of Vinyl Acetate at Ambient Temperature. Macromolecular Rapid Communications2015, 36, 2181-2185.

5.Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang, Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu, Zhengbiao Zhang*, Kan Yue* and Stephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like” Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered with Cyclic Polystyrenes. Macromolecules201447, 4160-4168.

6.Zhihao Huang,  Yanyan Zhou,  Zimu Wang,  Ying Li,  Wei Zhang,  Nianchen Zhou,  Zhengbiao Zhang*  and  Xiulin Zhu*. Recent Advances of CuAAC Click ReactionIBuilding Cyclic Polymer. Chinese Journal of Polymer Science201735, 317-341. Review article.

7.Zhaoxiong Cai, Weihong Lu, Feng Gao, Xiangqiang Pan, * Jian Zhu, Zhengbiao Zhang* Xiulin Zhu*. Diselenide-Labeled Cyclic Polystyrene with Multiple Responses: Facile Synthesis, Tunable Size, and Topology. Macromol. Rapid Commun.201637, 865-871.

8.Shuangshuang Zhang, Lu Yin, Wei Zhang*, Zhengbiao Zhang* and Xiulin Zhu*. Synthesis of Diverse Cyclic-Brush Polymers with Cyclic Polystyrene as Universal Template via Grafting-from Approach. Polym. Chem., 2016, 7, 2112-2120.

9.Qingqing Liu, Huaqiao Wu, Liuqiao Zhang, Yu Zhou, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu. RAFT polymerization of N-vinylpyrrolidone mediated by cyanoprop-2-yl-1-dithionaphthalate in the presence of a fluoroalcohol: the possibility of altering monomer properties by hydrogen bonding? Polym. Chem., 2016, 7, 2015-2021.

10.Yunshu Wang, Shuangshuang Zhang, Laibing Wang, Wei Zhang*, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu*. The Suzuki coupling reaction as a post-polymerization modification: a promising protocol for construction of cyclic-brush and more complex polymersPolym. Chem., 20156, 4669-4677.

11.Feng Gao, Xiangqiang Pan,* Jian Zhu, Zhengbiao Zhang*, Wei Zhang and Xiulin Zhu. Facile synthesis of well-defined redox responsive diselenide-labeled polymers via organoseleniummediated CRP and aminolysis. Polym. Chem., 201561367-1372.

12.Caiwei Fan, Chunlai Ding, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu*, and Xiulin Zhu. A Straightforward Method For Preparing Well-Defined Responsive Diselenide-containing Polymers Based on ATRP. Macromolecular Rapid Communications201536, 903-908.

13.Junfei Zhao, Yanyan Zhou, Yiwen Li, Xiangqiang Pan, Wei Zhang, Nianchen Zhou, Ke Zhang, Zhengbiao Zhang* and Xiulin Zhu*, Modular Construction of Macrocycle-based Topological Polymers via High-Efficient Thiol Chemistry, Polym. Chem., 201562879–2891.

14.Huaqiao Wu, Yingbo Wan, Wenxiang Wang, Yong Wang, Nianchen Zhou, Wei Zhang, Xiaohong Li,* Zhengbiao Zhang,* Xiulin Zhu, Hydrogen Bonding Promoting Controlled Radical Polymerization of 2-Vinyl Pyridine: Supramonomer for A Better Control, Polymer Chemistry20156, 2620-2625.

15.Feng Gao, Xiangqiang Pan, Jian Zhu, Zhengbiao Zhang, Wei Zhang, Xiulin Zhu Diselenocarbamates, Novel Initiators in ATRP of Styrene, J. Polym. Sci., Part A: Polym. Chem. 201553, 1927-1933.

16.Yuwei Gu, Junfei Zhao, Qingqing Liu, Xiangqiang Pan, Wei Zhang, Zhengbiao Zhang*, Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomers at room temperature: a promising catalyst system for CRP. Polym. Chem.20156, 359-363.

17.Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang, Zhiwei Lin, Xiulin Zhu, Qiang Fu, Zhengbiao Zhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis of macrocyclic giant surfactants tethered with two different polyhedral oligomeric silsesquioxanes at distinct ring locations via four consecutive click reactions. Polym. Chem., 20156, 827-837.

18.Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang*, Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymer to clickable thiol group via the versatile sodium azide. Polym. Chem.20145, 5546-5550.

19.Wenxiang Wang, Junfei Zhao, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerization in the Presence of Zero-Valent Metals: from Components to Precise Polymerization. Polym. Chem.20145, 3533-3546. Review Article.

20.Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, Wei Zhang, Zhengbiao Zhang* and Xiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groups from RAFT-made polystyrene: producing controllable bimodal molecular weight distribution.Polym. Chem20145, 1992-1998.

21.Zhigui Zheng, Wenxiang Wang, Yuan Zhou, Zhengbiao Zhang* and Xiulin Zhu*. Manganese(III) acetylacetonate initiated RAFT olymerizations: an alternative and versatile RAFT nitiator. Polym. Chem20145, 37-42.

22.Ye Cai, Jinjie Lu, Feng Zhou, Xiaoji Zhou, Nianchen Zhou*, Zhengbiao Zhang*, Xiulin Zhu* Cyclic Amphiphilic Random Copolymers Bearing Azobenzene Side Chains: Facile Synthesis and Topological Effects on Self-Assembly and Photoisomerization. Macromol. Rapid Commun.201435, 901−907.

23.Yuwei Gu, Junfei Zhao, Qingqing Liu, Nianchen Zhou, Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent iron (Fe(0)) mediated RAFT miniemulsion polymerization: a facile approach for the fabrication of Fe(0)-encapsulated polymeric nanoparticles Polym. Chem., 20145, 42154218.

24.Wenxiang Wang, Junfei Zhao, Huali Yu, Nianchen Zhou, Zhengbiao Zhang*, Xiulin Zhu*. Simultaneously improving controls over molecular weight andstereoregularity of Poly(4-vinylpyridine) via a hydrogen bonding-facilitated controlled radical polymerization. Polymer201354, 3248-3253.

25.Xiaofei Zhang, Yang Wu, Jun Huang, Xuelang Miao, Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-Mediated Radical Polymerization Of Styrene At Room Temperature. Chinese.J. Polym. Sci.201331702-712.

26.Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao, Zhengbiao Zhang* and Xiulin Zhu*. Hydrogen bonding assisted reversible-deactivation radical copolymerization of 4-vinylpyridine and styrene: a facile approach for adjusting polymerization behavior, polymer composition. Polym. Chem.201343575-3581.

27.Xiaofei Zhang, Wenxiang Wang, Kai Guo, Chrys Wesdemiotis, Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent metal catalyzed radical-induced adjustable removal/modification of thiocarbonylthio end groups of RAFT polymer at ambient temperature. Polym. Chem.20134637-644.

28.Yiyu Zhan, Zhengbiao Zhang*, Xiangqiang Pan, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. A Cyclic Selenium-Based Reversible Addition-Fragmentation Chain Transfer Agent Mediated Polymerization of Vinyl Acetate. J. Polym. Sci., Part A: Polym. Chem.2013511656-1663.

29.Wenxiang Wang, Junfei Zhao, Wei Zhang, Jian Zhu, Zhengbiao Zhang*, Xiulin Zhu*. Ligand-Free SET-DTLRP of MMA at Room Temperature. J. Polym. Sci., Part A: Polym. Chem.2013511872-1879.

30.Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. High-Effi ciency Preparation of Macrocyclic Polymers via a Circulatory Extraction-Cyclization Strategy. Macromol. Chem. Phys.2013214, 1107-1113.

31.Xing Zhu, Nianchen Zhou*, Jian Zhu, Zhengbiao Zhang*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*.A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryates in One Pot. Macromol. Rapid Commun.201334, 1014-1019.

32.Wenxiang Wang, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. Favorable hydrogen bonding in room-temperature Cu(0)-mediated controlled radical polymerization of 4-vinylpyridine. Polym. Chem.201232731-2734.

33.Junfei Zhao, Wenxiang Wang, Liangjiu Bai, Lili Zhou, Zhenping Cheng, Zhengbiao Zhang*, Xiulin Zhu*. Reversible-deactivation radical polymerizationmediated by CuSO4∙5H2O: an alternative and promising copper(II)-based catalyst. Polym. Chem.201233220-3223.

34.Lili Zhou, Zhengbiao Zhang*, Wenxiang Wang, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu*. Zero-Valent Bimetallic Iron/Copper Catalyzed SET-LRP: A Dual Activation by Zero-Valent Iron. J. Polym. Sci., Part A: Polym. Chem.201250936-943.

35.Wenxiang Wang, Zhengbiao Zhang*, Yang Wu, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. Ligand-Free Cu(0)-Mediated Controlled Radical Polymerization of Methyl Methacrylate at Ambient Temperature. J. Polym. Sci., Part A: Polym. Chem.201250711-719.

36.Huali Yu, Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. ATRP of Styrene Catalyzed by Elemental Fe(0) and Br2: An Easy and Economical ATRP Process. J. Polym. Sci., Part A: Polym. Chem.2012502182-2187.

37.Huali Yu, Yang Wu, Jinlong Gao, Wenxiang Wang, Zhengbiao Zhang* , Xiulin Zhu*. Copper(0)-Mediated Radical Copolymerization of Vinyl Acetate and Acrylonitrile in DMSO at Ambient Temperature. J. Polym. Sci., Part A: Polym. Chem.2012504983-4989.

38.Huali Yu, Qifeng Chen, Zhengbiao Zhang*, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. 60Co γ-irradiation-initiated RAFT polymerization of VAc at room temperature. React. Funct. Polym. 201272, 153-159.

39.Lili Zhou, Zhengbiao Zhang*, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu*. Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization of Methyl Methacrylate and Styrene at Ambient Temperature. Macromol. Chem. Phys.2012213439-446.

40.Qin Zhang, Zhengbiao Zhang* Wenxiang Wang, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. SET-RAFT of MMA Mediated by Ascorbic Acid-Activated Copper Oxide. J. Polym. Sci., Part A: Polym. Chem.2012501424-1433.

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