Topic： Description and Designed Synthesis of Metal-Organic Frameworks
Speaker： Professor Michael O’Keeffe (Arizona State University)
Time： 2014.5.28 pm4:00-5:00
Location：701#B501
Abstract:
Metal-organic frameworks (MOFs) are composed of metal-containing clusters (secondary building units joined by organic linkers, often carboxylates or azolates). They have remarkable, often very beautiful, open structures of unprecedentedly high surface area and porosity. Because of their remarkable properties for gas storage, separations, catalysis etc., their study has become the fastest-growing area of inorganic materials chemistry. Their structures are largely those of special favorable topologies which we have now enumerated. Accordingly structures of desired geometric properties can be targeted for designed synthesis - a process we call reticular chemistry (Yaghi, O’Keeffe et al., Nature, 2003). The methodology of enumerating topologies and their use on targeted synthesis will be demonstrated and profusely illustrated.
Michael O’Keeffe Curriculum Vitae：
Education --- University of Bristol, England
B. Sc. (1st class honours) 1954
Ph.D. (chemistry) 1958
D. Sc. (“for excellence in published research”) 1976
Employment
Assistant Professor in University of Bristol, England in 1963-1966 .
Associate Professor in University of Bristol, England in 1966-1970.
Professor in University of Bristol, England in 1970-1994.
Regents’ Professor in University of Bristol, England since 1994.
Recent professional activities
Many invited plenary/keynote lectures including recently：
---International Union of Crystallography (IUCr),
---International Mineralogical Association,
---International zeolite Association (IZA),
---Thomas Young lecturer (University College, London).
Honoree at “Fifty Years of Beautiful Structures” Symposium. Swanage, England 2012.
International Schools on periodic structures (taught with associate Dr. C. Bonneau) Fuzhou, China 2009, Zhuhai, China 2010,PAL, Pohang, Korea 2011, Stockholm, Sweden 2012. Lausanne, Switzerland (CECAM), 2013 Beijing, China 2013, KAUST, Saudi Arabia, 2014, Shanghai, China2014.
Member:
---IZA Zeolite Structure Commission
---MOF Advisory Council
---IUPAC MOF Nomenclature Commission
---MathCryst interest group, IUCr
Over 300 publications including 20 papers in Nature, 12 in Science, 3 in Physical Review Letters. Widely-cited monograph (with B. G. Hyde) crystal Structures I. Patterns and Symmetry (1996).
76 papers with over 100 citations. 10 with over 1000 citations, Hirsch index h = 86
On the world list of “100 highest impact chemists 2000-2010”: 3rd in impact (citations per paper), 12th in total citations. [see science Watch: http://www.sciencewatch.com/dr/sci/misc/Top100Chemists2000-10/]
Share in Newcomb Cleveland Prize for best paper in Science 2016
Most cited (>1000) publications as of May, 2014 (Google Scholar)：
1. Bond valence parameters for solids. Brese, N. E., O'Keeffe, M. Acta Crystallogr. B 47, 192-197 (1991). Times Cited: 4465
2. Reticular synthesis and the design of new materials. Yaghi, O. M., O'Keeffe, M., Ockwig, N., Chae, H. K., Eddadoudi, M., Kim. J. Nature 423, 705-714 (2003). Times cited: 4328
3. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Eddaoudi, M., Kim, J.. Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M., Yaghi, O. M. Science, 295, 469-472 (2002). Times cited:3914
4. Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Eddaoudi, M., Moler, D.B., Li, H., Chen, B. L., Reineke, T. M., O'Keeffe, M., Yaghi, O. M. Accts. Chem. Res. 34: 319-330 (2001). Times cited: 3781
5. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Li H., Eddaoudi, M., O'Keeffe, M., Yaghi, O. M. Nature 402, 276-279 (1999). Times cited: 3263
6. Hydrogen storage in microporous metal-organic frameworks . Yaghi, O. M., O'Keeffe, M., Ockwig, N., Chae, H. K., Eddadoudi, M., Kim. J. Science 300, 1127-1129 (2003). Times cited: 2710
7. A route to high surface area, porosity and inclusion of large molecules in crystals. Chae, H. K., Siberio-Pérez, D. Y., Kim, J., Go, Y., Eddaoudi, M., Matzger, A. J., O'Keeffe, M., Yaghi, O. M. Nature, 427 , 523-527 (2004).Times cited: 1533
8. Reticular chemistry: Occurrence and taxonomy of nets and grammar for the design of frameworks. Ockwig, N, W., Delgado-Friedrichs, O., O'Keeffe, M., Yaghi, O. M. Accts. Chem. Res. 38, 176-182 (2005). Times cited: 1509
9. Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units NL Rosi, J Kim, M Eddaoudi, B Chen, M O'Keeffe, O.M. Yaghi J. Am. Chem. Soc. 127, 1504-1518 (2005), Times cited: 1095
10. High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture R Banerjee, A Phan, B Wang, C Knobler, H Furukawa, M O'Keeffe, O.M. Yaghi Science 319 (5865), 939-943. Times cited: 1061