郎建平教授在Chem. Commun.发表研究论文

[PyH][{TpMo(μ3-S)4Cu3}412-I)]: a unique tetracubane cluster derived from the S–S bond cleavage and the iodide template effects and its enhanced NLO performances

Zhen-Hong Wei,ab   Chun-Yan Ni,a   Hong-Xi Li,a   Zhi-Gang Ren,a   Zhen-Rong Sunc and   Jian-Ping Lang*ab(郎建平)

 

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

c Department of Physics, East China Normal University, Shanghai 200062, P. R. China

 

Chem. Commun. 2013, 49, 4836-4838.

 

Reactions of [Et4N][TpMoS(S4)] with three equiv. of CuI in MeCN or in pyridine gave rise to one dicubane and one tetracubane anionic clusters, [Et4N]2[{TpMo(μ3-S)3Cu3I}2(μ-I){Cu(μ-I)24-I)2}] and [PyH][{TpMo(μ3-S)4Cu3}412-I)], and their third-order nonlinear optical (NLO) responses were greatly enhanced relative to that of the precursor.

 

链接: http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc41280f#!divAbstract