High Performance Miscible Polyetherimide/Bismaleimide Resins with Simultaneously Improved Integrated Properties Based on a Novel Hyperbranched Polysiloxane Having a High Degree of Branching

Bin Sun , Guozheng Liang *（梁国正）, Aijuan Gu *（顾嫒娟）, and Li Yuan

Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science & Engineering, College of Chemistry, Chemical Engineering, and Materials Science, Soochow University, Suzhou 215123, P. R. China

Ind. Eng. Chem. Res. 2013, 52, 5054–5065.

Amino-terminated hyperbranched polysiloxane (AHBSi) with high degree of branching (= 0.8) was synthesized by a control hydrolysis of γ-aminopropyl triethoxysilane (APTES) without using any catalyst. Besides, AHBSi was used as the compatibilizer of the miscible polyetherimide (PEI)/bismaleimide (BD) blend, and the influence of the content of AHBSi on the compatibility and integrated performance of the PEI/BD blend was systematically investigated. The corresponding investigation of the APTES/PEI/BD system was also carried out for comparison. Results show that although AHBSi and APTES have similar chemical segments, their different topological structures endow them with completely different effects. AHBSi can remarkably improve the compatibility between PEI and BD resin, and the AHBSi/PEI/BD system not only has obviously improved toughness and decreased brittleness while maintaining good stiffness. It also exhibits decreased dielectric constant and loss. Conversely, the APTES/PEI/BD system has greatly deteriorated compatibility and integrated performance. These interesting results demonstrate that AHBSi is a super multifunctional compatibilizer.

链接： http://pubs.acs.org/doi/pdf/10.1021/ie302665m