Ionic liquid–based click-ionogels
Yongyuan Ren, Jiangna Guo, Ziyang Liu, Zhe Sun, Yiqing Wu, Lili Liu, Feng Yan*(严锋)
Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China.
Sci. Adv.2019; 5 : eaax0648
Gels that are freeze-resistant and heat-resistant and have high ultimate tensile strength are desirable in practical applications owing to their potential in designing flexible energy storage devices, actuators, and sensors. Here, a simple method for fabricating ionic liquid (IL)–based click-ionogels using thiol-ene click chemistry under mild condition is reported. These click-ionogels continue to exhibit excellent mechanical properties and resilience after 10,000 fatigue cycles. Moreover, due to several unique properties of ILs, these click-ionogels exhibit high ionic conductivity, transparency, and nonflammability performance over a wide temperature range (−75° to 340°C). Clickionogel–based triboelectric nanogenerators exhibit excellent mechanical, freeze-thaw, and heat stability. These promising features of click-ionogels will promote innovative applications in flexible and safe device design.
链接:https://advances.sciencemag.org/content/advances/5/8/eaax0648.full.pdf