徐小平
姓名:徐小平

职称:研究员

苏州大学有机合成省级重点实验室秘书

部门:化学学院
联系方式:
电话:0512-65883304

Email:xuxp@suda.edu.cn


 课题组网站

1997.9-2001.6 南京师范大学化学院学士

2001.9-2004.6 苏州大学化学化工学院硕士

2004.8-2007.6 苏州大学化学化工学院博士

2007.8-至今    苏州大学材料与化学化工学部  教师

                         苏州大学有机合成省级重点实验室秘书


学术经历主持国家自然科学基金面上项目一项,完成国家基金委青年基金一项,作为第二参与人完成国家基金面上项目两项,完成江苏省省属高校自然科学基础研究项目、江苏省有机合成重点实验室开放课题各一项。以通讯作者的身份在国内外核心化学期刊如Chem. Commun.Org. Lett., Adv. Synth. Catal., Chem. Eur. J., ACS Appl. Mater. Interfaces等发表论文六十余篇,参与的项目获得了包括教育部自然科学二等奖、江苏省科学技术进步奖二等奖、中国石油与化学工业联合会科技进步二等奖在内的部、省、市级奖项六项。


教学经历担任本科生《有机化学》,《有机化学实验》,《化学与健康》等课程的教学任务。


研究领域催化剂导向及介质调控的高效及高选择性反应;有机功能分子的构筑及应用基础。


代表性论文及参编著作:

1. Treatment of Olefinic Amides with NBS in Water: Synthesis ofMonobromo- and Multibromobenzoxazines, Xu Zhang, Wen-Bin Cao, Xiao-Ping Xu*, Shun-Jun Ji*, Synthesis201951DOI: 10.1055/s-0037-1610724.

2. Dearomatization of Indoles via Azido Radical Addition andDioxygen Trapping To Access 2Azidoindolin-3-ols, Meng-Meng Xu, Wen-Bin Cao, Rao Ding, Hai-Yan Li, Xiao-Ping Xu*, Shun-Jun Ji*, Org. Lett201921, 6217.

3. Cooperation ofMn(III)/Brønsted Acid for the Synthesis of Quindoline Derivatives viaDehydroxylation/Azidation/Cyclization Cascade of Diaryl(1H-indol-2-yl)methanols with Trimethylsilyl Azide, Yu Zhou, Xiao-Ping Xu*, Shun-Jun Ji*,Org. Lett.2019212039.

4. Visible-light-induced oxidative ring expansion of indoles with amidines, Ling-Ling Zhang, Wen-Bin Cao, Xiao-Ping Xu*, Shun-Jun Ji*,Org. Chem. Front. 2019, 6, 1787.

5. CopperCatalyzed Sequential C(sp2)/C(sp3)−H Amination of 2Vinylanilines with NFluorobenzenesulfonimide, Wen-Bin Cao, Xiao-Ping Xu*, Shun-Jun Ji*, Adv. Synth, Catal.2019361, 1771.

6. Efficient synthesis of 2-arylquinazolin-4-amines via a copper-catalyzed diazidation and ring expansion cascade of 2-arylindoles, Meng-Meng Xu, Wen-Bin Cao, Xiao-Ping Xu*, Shun-Jun Ji*, Chem. Commun. 2018, 54, 12602.

7. Ag(I)-Promoted Dehydroxylation and Site-Selective 1,7-Disulfonylation of Diaryl(1Hindol-2-yl)methanols, Yu Zhou, Wen-Bin Cao, Ling-Ling Zhang, Xiao-Ping Xu*, Shun-Jun Ji*, J. Org. Chem. 201883, 6056.

8. Cooperation of Copper and Dioxygen for the Site-selective Construction of Benzo[1,5]diazocin-6(5H)-ones from Indoles and Enaminone Analogues, Wen-Bin Cao, Bei-Bei Liu, Xiao-Ping Xu*, Shun-Jun Ji*,Org. Chem. Front. 2018, 5, 1194.

9. Inkjet-Printed Quantum Dot Light-Emitting Diodes with an Air-Stable Hole Transport Material, Zhenhua Xing, Jinyong Zhuang*, Changting Wei, Dongyu Zhang, Zhongzhi Xie, Xiao-ping Xu*,  Shunjun Ji,  Jianxin Tang,  Wenming Su*,  and Zheng Cui,ACS Appl. Mater. Interfaces2017, 9, 16351.

10. Iron Catalysis for Modular Pyrimidine Synthesis through β-Ammoniation/Cyclization of Saturated Carbonyl Compounds with Amidines, Xue-Qiang Chu, Wen-Bin Cao, Xiao-Ping Xu*, Shun-Jun Ji*, J. Org. Chem. 201782, 1145.

11. Copper-catalyzed construction of eight-membered rings via oxidative ring expansion and intermolecular cyclization sequencing of indoles with amidines: efficient synthesis of benzo[1,3,5]triazocin-6(5H)-ones, Wen-Bin Cao, Xue-Qiang Chu, Yu Zhou, Ling Yin, Xiao-Ping Xu*, Shun-Jun Ji*, Chem. Commun. 2017, 53, 6601.

12. Palladium-Catalyzed Cyclization of Alkenes with Organohalides, Xue-Qiang Chu, Dan Liu, Zhen-Hua Xing, Xiao-Ping Xu*, Shun-Jun Ji*, Org. Lett. 201618, 776.

13. Copper-mediated radical alkylarylation of unactivated alkenes with acetonitrile leading to fluorenes and pyrroloindoles, Xue-Qiang Chu, Zhen-Hua Xing, Hua Meng, Xiao-Ping Xu*, Shun-Jun Ji*, Org. Chem. Front.2016, 3, 165.

14. TBAI-Catalyzed/Water-Assisted Double C-S Bond Formations: An Efficient Approach to Sulfides through Metal-Free Three-Component Reactions, Xue-Qiang Chu, Xiao-Ping Xu*,Shun-Jun Ji*, Chem. Eur. J.2016, 22, 14181.

15. One-Pot Synthesis of Allylic Sulfones, Ketosulfones, and Triflyl Allylic Alcohols from Domino Reactions of Allylic Alcohols with Sulfinic Acid under Metal-Free Conditions, Xue-Qiang Chu, Hua Meng, Xiao-Ping Xu*, Shun-Jun Ji*, Chem. Eur. J. 2015, 21, 11359.

16. Oxidative C(sp3)–H functionalization of acetonitrile and alkanes with allylic alcohols under metal-free conditions, Xue-Qiang Chu, Hua Meng, You Zi, Xiao-Ping Xu*, Shun-Jun Ji*, Org. Chem. Front. 20152, 216.

17. Metal-Free Oxidative Radical Addition of Carbonyl Compounds to α,α-Diaryl Allylic Alcohols: Synthesis of Highly Functionalized Ketones, Xue-Qiang Chu, Hua Meng, You Zi, Xiao-Ping Xu*, Shun-Jun Ji*, Chem. Eur. J. 2014, 20, 17198.

18. Metal-free oxidative direct C(sp3)–H bond functionalization of ethers with α,α-diaryl allylic alcohols, Xue-Qiang Chu, Hua Meng, You Zi, Xiao-Ping Xu*, Shun-Jun Ji*, Chem. Commun.201450, 9718.

19. Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration, Xue-Qiang Chu, You Zi, Hua Meng, Xiao-Ping Xu*, Shun-Jun Ji*, Chem. Commun201450, 7642.